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Published in 2025 at "Chemsuschem"
DOI: 10.1002/cssc.202500392
Abstract: Molecular metal complexes form an important class of catalysts for the electroreduction of CO2 (CO2RR) to carbon monoxide (CO) or formic acid (HCOOH), key processes in the context of the requested exploration of novel sources…
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Keywords:
molecular catalyst;
combining molecular;
gas;
flue gas ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08884
Abstract: We report a strategy to integrate atomically dispersed iron within a heterogeneous nitrogen-doped carbon (N-C) support, inspired by routes for metalation of molecular macrocyclic iron complexes. The N-C support, derived from pyrolysis of a ZIF-8…
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Keywords:
molecular catalyst;
atomically dispersed;
prepare atomically;
catalyst synthesis ... See more keywords
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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12775
Abstract: The integration of heterogeneous electrocatalysis and molecular catalysis is a promising approach to designing new catalysts for the oxygen evolution reaction (OER) and other processes. We recently showed that the electrostatic potential drop across the…
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Keywords:
molecular catalyst;
catalyst;
water;
voltage driven ... See more keywords
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Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c12783
Abstract: Nitrate (NO3-) is a common nitrogen-containing contaminant in agricultural, industrial, and low-level nuclear wastewater that causes significant environmental damage. In this work, we report a bioinspired Cr-based molecular catalyst incorporated into a redox polymer that…
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Keywords:
catalyst;
molecular catalyst;
selective reduction;
ammonium ... See more keywords
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Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-54026-2
Abstract: The selective photoreduction of CO2 in aqueous media based on earth-abundant elements only, is today a challenging topic. Here we present the anchoring of discrete molecular catalysts on organic polymeric semiconductors via covalent bonding, generating…
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Keywords:
catalyst;
molecular catalyst;
water;
photoreduction ... See more keywords
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Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc04222a
Abstract: Heavy metal-free CuInS2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO2 reduction for the first time. A photocurrent of 25 μA…
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Keywords:
cuins2 quantum;
molecular catalyst;
free cuins2;
heavy metal ... See more keywords
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Published in 2025 at "Chemical Science"
DOI: 10.1039/d5sc04667j
Abstract: The escalating global challenge of plastic waste calls for innovative recycling solutions that overcome the high energy requirements of traditional chemical recycling and the inefficiency of enzymatic methods. Here, inspired by the structure of Salen-based…
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Keywords:
catalyst;
molecular catalyst;
salen molecular;
multifunctional salen ... See more keywords
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Published in 2025 at "National Science Review"
DOI: 10.1093/nsr/nwaf198
Abstract: ABSTRACT Molecular catalysts facilitate electrochemical conversion by changing their oxidation states to transfer electrons. However, this redox-mediated mechanism features stepwise electron transfer and substrate activation in separate elementary steps, thereby resulting in an inherent loss…
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Keywords:
catalyst;
molecular catalyst;
redox decoupled;
electrocatalysis ... See more keywords