Photoelectrocatalytic Synthesis of Hydrogen Peroxide by Molecular Copper‐Porphyrin Supported on Titanium Dioxide Nanotubes
Sign Up to like & getrecommendations! Published in 2018 at "Chemcatchem"
DOI: 10.1002/cctc.201702055
Abstract: We report on a self‐assembled system comprising a molecular copper‐porphyrin photoelectrocatalyst, 5‐(4‐carboxy‐phenyl)‐10,15,20‐triphenylporphyrinatocopper(II) (CuTPP‐COOH), covalently bound to self‐organized, anodic titania nanotube arrays (TiO2 NTs) for photoelectrochemical reduction of oxygen. Visible light irradiation of the porphyrin‐covered TiO2… read more here.
Keywords: copper porphyrin; hydrogen; molecular copper; tio2 nts ... See more keywords
Electrocatalytic Water Oxidation Activity of Molecular Copper Complexes: Effect of Redox-Active Ligands.
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DOI: 10.1021/acs.inorgchem.1c03537
Abstract: Two molecular copper(II) complexes, (NMe4)2[CuII(L1)] (1) and (NMe4)2[CuII(L2)] (2), ligated by a N2O2 donor set of ligands [L1 = N,N'-(1,2-phenylene)bis(2-hydroxy-2-methylpropanamide), and L2 = N,N'-(4,5-dimethyl-1,2-phenylene)bis(2-hydroxy-2-methylpropanamide)] have been synthesized and thoroughly characterized. An electrochemical study of 1… read more here.
Keywords: oxidation; copper; water oxidation; molecular copper ... See more keywords