Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.
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DOI: 10.1039/c6dt04654a
Abstract: Molecular magnesium hydride with a terminal metal-hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare MgH-Al interaction. read more here.
Keywords: molecular magnesium; magnesium; triazacyclononane; type ligand ... See more keywords