Transamidation-Driven Molecular Pumps
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c06807
Abstract: We report a new class of synthetic molecular pumps that use a stepwise information ratchet mechanism to achieve the kinetic gating required to sequester their macrocyclic substrates from bulk solution. Threading occurs as a result… read more here.
Keywords: transamidation; rotaxane; transamidation driven; pump ... See more keywords
Polyrotaxanes and the pump paradigm.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d2cs00194b
Abstract: The year 2022 marks the 30th anniversary of the first reports of polyrotaxanes in the scientific literature. During the past three decades, many combinations of molecular rings and polymer chains have been synthesised and characterised.… read more here.
Keywords: pump paradigm; chemistry; polymer chains; polyrotaxanes pump ... See more keywords