Calorimetric distinction between the inter- and intra-molecular rearrangement processes in alkylcyclohexane liquids by means of spatial confinement
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.113359
Abstract: Abstract We report an investigation, by means of adiabatic calorimetry, on the thermal properties of ethylcyclohexane (ECH) confined to within silica-gel mesoscopic pores with an average pore size of 6 nm. As a result of confinement,… read more here.
Keywords: relaxation; occurring within; molecular rearrangement; confinement ... See more keywords
Molecular Rearrangement of Four Typical Grape Free Terpenes in the Wine Environment.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of agricultural and food chemistry"
DOI: 10.1021/acs.jafc.2c07576
Abstract: In order to analyze the molecular rearrangement of terpenes in wine during aging, the changes in linalool, α-terpineol, nerol, and geraniol in model wine were investigated in the dark at low temperature for 90 days.… read more here.
Keywords: molecular rearrangement; rearrangement four; four typical; linalool ... See more keywords
A facile route to 1H- and 2H-indazoles from readily accessible acyl hydrazides by exploiting a novel aryne-based molecular rearrangement.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc06556j
Abstract: Herein we report the transformation of readily synthesised acyl hydrazides into 2-hydrazobenzophenones via a novel molecular rearrangement pathway using aryne chemistry. The developed reaction protocol is performed under relatively mild conditions and is tolerant of… read more here.
Keywords: facile route; molecular rearrangement; route indazoles; indazoles readily ... See more keywords