Solvent-Induced Structural Transformation and Luminescence Response in a Dumbbell-Shaped Crystalline Molecular Rotor.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03504
Abstract: Crystalline molecular rotors constitute a new class of stimuli-responsive molecular materials owing to inherent molecular dynamics. However, beyond the molecular level, the role of molecular packings on the bulk structures and related properties has yet… read more here.
Keywords: molecular rotor; crystalline molecular; transformation; rotor ... See more keywords
A Molecular Rotor Driven by an Electric Field on Graphene
Sign Up to like & getrecommendations! Published in 2025 at "ACS Omega"
DOI: 10.1021/acsomega.5c06030
Abstract: We propose a scheme for driving a dipolar molecular rotor to rotate continuously by applying an external electric field: the dipolar rotor is fixed on a graphene sheet via a metal atom to facilitate the… read more here.
Keywords: molecular rotor; rotor; electric field; dipolar rotor ... See more keywords
Thiophene-Extended Fluorescent Nucleosides as Molecular Rotor-Type Fluorogenic Sensors for Biomolecular Interactions.
Sign Up to like & getrecommendations! Published in 2023 at "ACS sensors"
DOI: 10.1021/acssensors.2c02617
Abstract: Fluorescent molecular rotors are versatile tools for the investigation of biomolecular interactions and the monitoring of microenvironmental changes in biological systems. They can transform invisible information into a fluorescence signal as a straightforward response. Their… read more here.
Keywords: biomolecular interactions; thiophene extended; rotor; rotor type ... See more keywords
Strategic Modulation of Polarity and Viscosity Sensitivity of Bimane Molecular Rotor-Based Fluorophores for Imaging α-Synuclein.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c17933
Abstract: Molecular rotor-based fluorophores (RBFs) that are target-selective and sensitive to both polarity and viscosity are valuable for diverse biological applications. Here, we have designed next-generation RBFs based on the underexplored bimane fluorophore either through a… read more here.
Keywords: based fluorophores; polarity viscosity; molecular rotor; polarity ... See more keywords
Dual-functional fluorescent molecular rotor for endoplasmic reticulum microviscosity imaging during reticulophagy.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc00300b
Abstract: The microviscosity change associated with reticulophagy is an important component for studying endoplasmic reticulum (ER) stress disorders. Here, a BODIPY-arsenicate conjugate 1-based fluorescent molecular rotor was designed to covalently bind vicinal dithiol-containing proteins in the… read more here.
Keywords: fluorescent molecular; molecular rotor; endoplasmic reticulum; microviscosity ... See more keywords
A fluorogenic BODIPY molecular rotor as an apoptosis marker.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03242h
Abstract: Based on a BODIPY molecular rotor and a zinc-dipicolylamine receptor, we designed a fluorogenic probe for the detection of apoptosis. Being poorly emissive in solution and with healthy cells, it selectively binds phosphatidylserine of early… read more here.
Keywords: rotor apoptosis; fluorogenic bodipy; molecular rotor; bodipy molecular ... See more keywords
CAl11-: a molecular rotor with a quasi-planar tetracoordinate carbon.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00855j
Abstract: In this work, we analyzed the bonding and fluxional character of the global minimum of CAl11-. Its structure is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on… read more here.
Keywords: cal11 molecular; molecular rotor; tetracoordinate carbon; planar tetracoordinate ... See more keywords
CBe4H6: a molecular rotor with a built-in on-off switch.
Sign Up to like & getrecommendations! Published in 2024 at "Nanoscale"
DOI: 10.1039/d3nr05695c
Abstract: It is highly challenging to control (stop and resume as needed) molecular rotors because their intramolecular rotations are electronically enabled by delocalized σ bonding, and the desired control needs to be able to destroy and… read more here.
Keywords: cbe4h6; cbe4h6 molecular; rotation; molecular rotor ... See more keywords
A Novel TICT-based Molecular Rotor: Synthesis, Crystal structure and Application in High Resolution Imaging of Sweat Pores
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Materials Chemistry C"
DOI: 10.1039/d4tc02400a
Abstract: We report the synthesis, characterization and X-ray crystal structure of naphthalimide–methoxyquinoline (NI-HQ) based molecular rotor. NI-HQ crystallizes in a triclinic crystal system with a centrosymmetric Pi space group and it... read more here.
Keywords: synthesis; molecular rotor; based molecular; crystal structure ... See more keywords
Switching G-quadruplex to parallel duplex by molecular rotor clustering
Sign Up to like & getrecommendations! Published in 2022 at "Nucleic Acids Research"
DOI: 10.1093/nar/gkac811
Abstract: Abstract Switching of G-quadruplex (G4) structures between variant types of folding has been proved to be a versatile tool for regulation of genomic expression and development of nucleic acid-based constructs. Various specific ligands have been… read more here.
Keywords: quadruplex parallel; parallel duplex; rotor clustering; molecular rotor ... See more keywords
Singularity-free quantum tracking control of molecular rotor orientation
Sign Up to like & getrecommendations! Published in 2018 at "Physical Review A"
DOI: 10.1103/physreva.98.043429
Abstract: Quantum tracking control aims to identify applied fields to steer the expectation values of particular observables along desired paths in time. The associated temporal fields can be identified by inverting the underlying dynamical equations for… read more here.
Keywords: molecular rotor; orientation; control; tracking control ... See more keywords