Partial alignment, residual dipolar couplings and molecular symmetry in solution NMR.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of biomolecular NMR"
DOI: 10.1007/s10858-019-00256-2
Abstract: Residual dipolar couplings (RDCs) and residual anisotropic chemical shifts (RACSs) are produced by the partial alignment of solution NMR samples. RDCs and RACSs yield high-resolution structural and dynamic information on the orientation of bonds and… read more here.
Keywords: solution nmr; residual dipolar; symmetry; molecular symmetry ... See more keywords
Hendecanuclear [Cu6Gd5] magnetic cooler with high molecular symmetry of D3h
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2020.05.018
Abstract: Abstract A new family of isostructural 3d-4f polymetallic complexes, formulated as [Cu6Ln5(µ3-OH)9 (C4H8O2N)6(C5H4ON)6(H2O)9]·(ClO4)6·(H2O)22 (Ln = Pr, 1; Nd, 2; Sm, 3; Eu, 4; Gd, 5), was successfully isolated through the simple hydrolysis reaction of 2-aminoisobutyric… read more here.
Keywords: high molecular; hendecanuclear cu6gd5; symmetry d3h; molecular symmetry ... See more keywords
Stacking Control by Molecular Symmetry of Sterically Protected Phthalocyanines
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25235552
Abstract: The synthesis and characterization of two phthalocyanine (Pc) structural isomers, 1 and 2, in which four 2,6-di(hexyloxy)phenyl units were attached directly to the 1,8,15,22- or 1,4,15,18-positions of the Pc rings, are described. Both Pcs 1… read more here.
Keywords: symmetry sterically; stacking control; symmetry; molecular symmetry ... See more keywords
Impact of Molecular Symmetry/Asymmetry on Insulin-Sensitizing Treatments for Type 2 Diabetes
Sign Up to like & getrecommendations! Published in 2022 at "Symmetry"
DOI: 10.3390/sym14061240
Abstract: Although the advantages and disadvantages of asymmetrical thiazolidinediones as insulin-sensitizers have been well-studied, the relevance of symmetry and asymmetry for thiazolidinediones and biguanides has scarcely been explored. Regarding symmetrical molecules, only one thiazolidinedione and no… read more here.
Keywords: symmetry asymmetry; type diabetes; molecular symmetry; insulin ... See more keywords
Molecular Symmetry of Permethylated β-Cyclodextrins upon Complexation
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DOI: 10.3390/sym14102214
Abstract: The Cn molecular symmetry implicated by the schemes with which cyclodextrins (CDs), the well-known cyclic oligosaccharides, are introduced in the literature, is not valid. Numerous studies have shown that CDs are rather flexible with their… read more here.
Keywords: complexation; symmetry permethylated; upon complexation; permethylated cyclodextrins ... See more keywords