Intensity Fluctuations in Single-Molecule Surface-Enhanced Raman Scattering.
Sign Up to like & getrecommendations! Published in 2019 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.8b00563
Abstract: Around 20 years ago, the first reports of single-molecule surface-enhanced Raman scattering (SM-SERS) caused a revolution in nanotechnology. Several researchers were quick to recognize the importance of a technique that can provide molecular vibrational fingerprinting… read more here.
Keywords: raman scattering; single molecule; molecule surface; enhanced raman ... See more keywords
Rigid Body Approximation for the Anharmonic Description of Molecule-Surface Vibrations.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.2c00597
Abstract: We present an anharmonic approach for molecule-surface vibrations that employs rigid body coordinates, based on the Rodrigues rotation formula, to describe curvilinear displacements (rotations and translations) of the molecule along normal modes. These displacements are… read more here.
Keywords: ch4; mof; molecule surface; surface vibrations ... See more keywords
Classical Molecule–Surface Scattering in a Quantum Spirit: Application to H2/Pd(111) Nonactivated Sticking
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b04829
Abstract: The semiclassical initial value representation is used to derive a simple expression for the sticking probability in nonactivated dissociative chemisorptions of diatomic molecules. This expression, whose calculation requires only the running of classical trajectories, takes… read more here.
Keywords: quantum spirit; molecule surface; surface scattering; spirit application ... See more keywords
Exploring the Molecular Conformation Space by Soft Molecule–Surface Collision
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c09933
Abstract: Biomolecules function by adopting multiple conformations. Such dynamics are governed by the conformation landscape whose study requires characterization of the ground and excited conformation states. Here, the conformational landscape of a molecule is sampled by… read more here.
Keywords: molecule; molecule surface; surface collision; conformation ... See more keywords
A general method for controlling and resolving rotational orientation of molecules in molecule-surface collisions
Sign Up to like & getrecommendations! Published in 2017 at "Nature Communications"
DOI: 10.1038/ncomms15357
Abstract: The outcome of molecule–surface collisions can be modified by pre-aligning the molecule; however, experiments accomplishing this are rare because of the difficulty of preparing molecules in aligned quantum states. Here we present a general solution… read more here.
Keywords: general method; molecule; molecule surface; surface ... See more keywords
Dynamic plasmonic nano-traps for single molecule surface-enhanced Raman scattering.
Sign Up to like & getrecommendations! Published in 2017 at "Nanoscale"
DOI: 10.1039/c7nr02406a
Abstract: Intense electric fields at the nanoscale are essential for single molecule surface-enhanced Raman scattering (SERS) detection. Such fields can be achieved in plasmonic nano-gaps between nanoparticles and metal films through hybridization of surface plasmons. The… read more here.
Keywords: surface enhanced; single molecule; molecule surface; enhanced raman ... See more keywords