Synthesis and structure of two isomers of a molybdenum(II) 2-butyne complex stabilized by bioinspired S,N-bidentate ligands.
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DOI: 10.1107/s2053229622002029
Abstract: The synthesis and structural determination of two isomers of the molybdenum(II) complex (η2-but-2-yne)carbonylbis[2-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)benzenethiolato-κ2N,S]molybdenum(II), [Mo(C11H12NOS)2(C4H6)(CO)] or Mo(CO)(C2Me2)(S-Phoz)2, are presented. The N,N-cis-S,S-trans isomer 1 shows quite different bond lengths to the metal atom [Mo-N = 2.4715 (10) versus 2.3404 (11) Å;… read more here.
Keywords: two isomers; structure two; bond lengths; synthesis structure ... See more keywords