Incorporation of a dioxo-molybdenum (VI) complex into a titanium-functionalized Zr(IV)-Based metal-organic framework
Sign Up to like & getrecommendations! Published in 2020 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110359
Abstract: Abstract The use of Titanium-based Metal-Organic Frameworks (MOFs) as substitutes for titanium dioxide in photocatalytic applications is a recent topic of study. A promising approach is to perform a titanium exchange within a zirconium-based MOF… read more here.
Keywords: molybdenum complex; dioxo molybdenum; metal organic; titanium ... See more keywords
Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(VI) complex with H2O2 as an oxidant
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DOI: 10.1039/c8ra05969a
Abstract: Here, we have described the synthesis, characterization and catalytic activity of a dioxo-molybdenum(VI) complex supported on functionalized Merrifield resin (MR-SB-Mo). The functionalization of Merrifield resin (MR) was achieved in two-steps viz. carbonylation (MR-C) and Schiff… read more here.
Keywords: molybdenum complex; h2o2 oxidant; merrifield resin;
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords
Synthesis and structure of a pyridine-stabilized silanone molybdenum complex and its reactions with PMe3 and acetone.
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DOI: 10.1039/d2dt02560d
Abstract: Silanones (OSiR2) are highly reactive species that readily convert to oligomeric siloxane (O-SiR2)n. The coordination of silanones to transition metal fragments to afford silanone-coordinated complexes is a reliable silanone stabilization method. Herein, a pyridine-stabilized silanone… read more here.
Keywords: silanone molybdenum; pyridine; molybdenum complex; sime3 ... See more keywords