Oxido-alcoholato/thiolato-molybdenum(VI) complexes with a dithiolene ligand generated by oxygen atom transfer to the molybdenum(IV) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.10.001
Abstract: Abstract Oxido-alcoholato- and oxido-thiolato-molybdenum(VI) complexes bearing two ene-1,2-dithiolate ligands (cyclohexene-1,2-dithiolate) are prepared as synthetic models of molybdenum(VI) reaction centers of dimethyl sulfoxide reductase family of molybdenum enzymes. These complexes are prepared by oxygen atom transfer… read more here.
Keywords: thiolato molybdenum; molybdenum complexes; molybdenum; atom transfer ... See more keywords
Molybdenum complexes of poly[(methylthio)methyl]borates
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.04.036
Abstract: Abstract Organometallic molybdenum compounds bearing poly[(methylthio)methyl]borates, [(η3-C3H5)Mo(CO)2(κ3-PhTt)] and [Bu4N][{(η3-C3H5)Mo(CO)2Cl}2(κ2:κ2-RTt)], where PhTt = phenyltris[(methylthio)methyl]borate and RTt = tetrakis[(methylthio)methyl]borate, have been obtained by ligand exchange reaction from [(η3-C3H5)Mo(CO)2(NCMe)2Cl] and appropriate borate. The PhTt ligand provides tridentate face-capping coordination to the central… read more here.
Keywords: methyl; poly methylthio; molybdenum complexes; methyl borates ... See more keywords
Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01993
Abstract: During our attempts to prepare paddlewheel actinide-molybdenum complexes of the type [(X)An(MesNPR2)3Mo(CO)3] (Mes= 2,4,6-trimethylphenyl; X = Cl or I; An = U or Th; R = iPr or Ph) we have found that under certain… read more here.
Keywords: ketimido; actinide molybdenum; molybdenum complexes; preparation heterobimetallic ... See more keywords
Reactions of Silanone(silyl)tungsten and -molybdenum Complexes with MesCNO, (Me2SiO)3, MeOH, and H2O: Experimental and Theoretical Studies
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.6b00958
Abstract: Reactions of silanone(silyl)tungsten and -molybdenum complexes Cp*(OC)2M{O═SiMes2(DMAP)}(SiMe3) (M = W (1a), Mo (1b), Cp* = η5-C5Me5, Mes = 2,4,6-Me3C6H2, DMAP = 4-(Me2N)C5H4N) with MesCNO, (Me2SiO)3, MeOH, and H2O were investigated. No silanone trapping product was… read more here.
Keywords: tungsten molybdenum; product; reactions silanone; molybdenum complexes ... See more keywords
Molybdenum(ii) complexes with p-substituted BIAN ligands: synthesis, characterization, biological activity and computational study.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00469f
Abstract: New complexes [Mo(η3-C3H5)X(CO)2(4-Y-BIAN)] (4-Y-BIAN = bis(4-Y-phenyl)-acenaphthenequinonediimine), with X = Br and Y = H, Me, OMe, COOH and X = Cl, Y = OMe, as well as the cation with X = NCMe and Y… read more here.
Keywords: synthesis characterization; complexes substituted; molybdenum complexes; bian ligands ... See more keywords