Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies.
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DOI: 10.1039/d1dt04212b
Abstract: The tungsten dinitrogen complex [W(N2)(PMe2PPPh2)] (2) (PMe2PPPh2 = [2-({bis[3-(diphenylphosphino)propyl]-phosphino}methyl)-2-methylpropane-1,3-diyl]bis(dimethylphosphine)) is synthesized and characterized by X-ray diffraction as well as IR and NMR spectroscopies, showing strong analogies to its molybdenum analogue [Mo(N2)(PMe2PPPh2)] (1). Whereas cyclic voltammetry… read more here.
Keywords: molybdenum dinitrogen; tungsten molybdenum; dinitrogen complexes; supported pentadentate ... See more keywords