Synthesis of Molybdenum Imido 2-Adamantylidene Complexes through α Hydrogen Abstraction
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DOI: 10.1021/acs.organomet.0c00244
Abstract: Addition of 2-adamantylMgBr in diethyl ether to Mo(NAr)2(Cl)2(DME) (Ar = 2,6-i-Pr2C6H3) gave Mo(NAr)2(2-Ad)2 (2-Ad = 2-adamantyl, DME = 1,2-dimethoxyethane), from which Mo(NAr)(Adene)(OTf)2(DME) (1... read more here.
Keywords: complexes hydrogen; imido adamantylidene; adamantylidene complexes; synthesis molybdenum ... See more keywords
Reaction Mechanism of Ring-Closing Metathesis with a Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Catalyst
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DOI: 10.1021/acs.organomet.0c00311
Abstract: DFT calculations were carried out to explore all relevant pathways for the ring-closing metathesis (RCM) reaction of a cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) catalyst wit... read more here.
Keywords: imido alkylidene; cationic molybdenum; alkylidene heterocyclic; molybdenum imido ... See more keywords
Tuning the Latent Behavior of Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes in Dicyclopentadiene Polymerization
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DOI: 10.1021/acs.organomet.0c00740
Abstract: We report the synthesis of O- and N-chelated hexacoordinated molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate and pentacoordinated molybdenum imido alkylidene NHC monotriflate monoalkoxide complexes and their use as thermally latent and in some cases… read more here.
Keywords: molybdenum imido; alkylidene heterocyclic; polymerization; imido alkylidene ... See more keywords