Molybdenum-Mediated Coupling of Carbon Monoxide to a C3 Product on a Single Metal Site.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00266
Abstract: The synthesis and characterization of a series of naphthalenediyl-diphosphine molybdenum complexes are reported. A novel dicarbonyl-Mo complex (3) converts to a bis(siloxy)acetylene complex (5) upon reduction and treatment with a silyl electrophile, Me3SiCl. This process… read more here.
Keywords: coupling carbon; molybdenum; monoxide product; mediated coupling ... See more keywords
Mechanism of the Molybdenum-Mediated Cadogan Reaction
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DOI: 10.1021/acsomega.8b01278
Abstract: Oxygen atom transfer reactions are receiving increasing attention because they bring about paramount transformations in the current biomass processing industry. Significant efforts have therefore been made lately in the development of efficient and scalable methods… read more here.
Keywords: molybdenum mediated; reaction; cadogan reaction; mediated cadogan ... See more keywords
Molybdenum(V)-mediated switching of the C(sp2)-Se bond of phenylselenyl-functionalized arenes or heterocycles under mild conditions.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01119d
Abstract: Molybdenum(V)-mediated cleavage of C(sp2)-Se bond and C(sp2)-H bond as well as intramolecular oxidative C(sp2)-Se coupling reaction of phenylselenyl-functionalized arenes or heterocycles has been developed. Three kinds of benzoselenophene frameworks were constructed through this reaction with… read more here.
Keywords: arenes heterocycles; functionalized arenes; sp2 bond; phenylselenyl functionalized ... See more keywords
Molybdenum-Mediated One-Pot Synthesis of Pyrazoles from Isoxazoles
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DOI: 10.1055/s-0039-1690615
Abstract: A one-pot approach for the direct synthesis of substituted pyrazoles from isoxazoles is reported. The process involves isoxazole N–O bond cleavage mediated by a molybdenum complex, in situ hydrolysis of the resulting β-amino enone to… read more here.
Keywords: molybdenum mediated; mediated one; one pot; pyrazoles isoxazoles ... See more keywords