Cis- and trans molybdenum oxo complexes of a prochiral tetradentate aminophenolate ligand: Synthesis, characterization and oxotransfer activity
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114312
Abstract: Abstract Reaction of [MoO2Cl2(dmso)2] with the tetradentate O2N2 donor ligand papy [H2papy = N-(2-hydroxybenzyl)-N-(2-picolyl)glycine] leads to formation of the dioxomolybdenum(VI) complex [MoO2(papy)] (1) as a mixture of cis and trans isomers. Recrystallization from methanol furnishes solid cis-1,… read more here.
Keywords: cis; molybdenum oxo; trans molybdenum; cis trans ... See more keywords
Top-down synthesis of polyoxometalate-like sub-nanometer molybdenum-oxo clusters as high-performance electrocatalysts†
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc05469c
Abstract: The top-down fabrication of catalytically active molecular metal oxide anions, or polyoxometalates, is virtually unexplored, although these materials offer unique possibilities, for catalysis, energy conversion and storage. Here, we report a novel top-down route, which… read more here.
Keywords: molybdenum oxo; oxo clusters; nanometer molybdenum; performance ... See more keywords
Polyoxometalate-like sub-nanometer molybdenum(vi)-oxo clusters for sensitive, selective and stable H2O2 sensing.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc03758c
Abstract: Polyoxometalate-like molybdenum(vi)-oxo clusters ([Mo-oxo]n, n = 1-20) deposited on high surface-area carbon are developed as a biosensor for non-enzymatic electrochemical H2O2 detection. The sensor exhibits excellent electrocatalytic performance with a low detection limit, wide linear… read more here.
Keywords: molybdenum oxo; polyoxometalate like; oxo clusters; h2o2 ... See more keywords