Comparison of molybdenum and rhenium oxo bis-pyrazine-dithiolene complexes - in search of an alternative metal centre for molybdenum cofactor models.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04237c
Abstract: A pair of structurally precise analogues of molybdenum and rhenium complexes, [Et4N]/K2[MoO(prdt)2] and K[ReO(prdt)2] (prdt = pyrazine-2,3-dithiolene), were synthesized. These complexes serve as structural models for the active sites of bacterial molybdenum cofactor containing enzymes.… read more here.
Keywords: molybdenum rhenium; molybdenum cofactor; pyrazine dithiolene; metal ... See more keywords
Molybdenum and rhenium disulfide synthesis via high-pressure carbonate melt
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce00188c
Abstract: A new method is shown for the crystallisation of molybdenum and rhenium disulfide from high pressure liquid carbonate flux. Crystal size ranges from 10s to 100s of micrometres. read more here.
Keywords: carbonate; molybdenum rhenium; rhenium disulfide; high pressure ... See more keywords
Sorptive separation of molybdenum(VI) from rhenium-containing solutions
Sign Up to like & getrecommendations! Published in 2017 at "Russian Journal of Applied Chemistry"
DOI: 10.1134/s1070427217040061
Abstract: It is shown that Purolite S957 cation-exchange resin containing phosphonic-acid and sulfonic groups is capable of selectively sorbing molybdenum(VI) in the presence of rhenium(VII) in solution. read more here.
Keywords: rhenium containing; sorptive separation; molybdenum rhenium; rhenium ... See more keywords