Crystal structures of mono- and binuclear neodymium diarylphosphate complexes and their catalytic activity in 1,3-diene polymerization
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DOI: 10.1007/s11224-018-1132-2
Abstract: Molecular structures of three neodymium tris(organophosphate) complexes of different types have been determined: mononuclear complex {Nd[(2,6-Me2C6H3-O)2PO2]3[(2,6-Me2C6H3-O)2PO2H]3} (1), binuclear complexes {Nd2[(2,6-Me2C6H3-O)2POO]6[(2,6-Me2C6H3-O)2PO2H]} (2) and {Nd2[(2,4-Cl2-6-MeC6H3O)2PO2]6(H2O)2(OCMe2)2} (3). Organophosphate ligands demonstrate κ1O and κ2O,O′ terminal, as well as μ2-κ1O:κ1O'… read more here.
Keywords: structures mono; crystal structures; catalytic activity; neodymium ... See more keywords
Interactions of Verkade's Superbase with Strong Lewis Acids: From Labile Mono- and Binuclear Lewis Acid-Base Complexes to Phosphenium Cations.
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DOI: 10.1021/acs.inorgchem.7b01719
Abstract: A series of mono- and binuclear Lewis acid-base complexes of the formulas N[CH2CH2N(Pri)]3P→LA [LA = BH3 (8), Ga(C6F5)3 (10), GaCl3 (11)], LA←N[CH2CH2N(Pri)]3P [LA = Al(C6F5)3 (6a), AlMe3 (6b), AlEt3 (6c), AlBui3 (6d), BF3 (13)], and… read more here.
Keywords: lewis acid; pri; ch2ch2n pri; base ... See more keywords
Study of the Molecular Properties of Mono- and Binuclear Metal s-Indacenyl Complexes with Ir, Rh, and Re: A Theoretical Approach
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DOI: 10.1155/2017/9101720
Abstract: Density functional theory (DFT) calculations were performed on a new family of mono- and bimetallic complexes, containing 4,8-(paracyclophane)-1,5-dihydro-s-indacene as the bridging ligand between the two metallic centers and different ancillary ligands. The s-indacene was blocked… read more here.
Keywords: properties mono; study molecular; molecular properties; indacenyl ... See more keywords