Synthesis of strained complexes of arene d6 metals with benzoylthiourea and their spectral studies
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DOI: 10.1016/j.jorganchem.2018.05.023
Abstract: Abstract Halide bridged arene d6 platinum group metal precursors on treatment with thiourea derivatives (L1 and L2) yielded a series of neutral mono-dentate complexes (1–8). In general complexes have been formulated as [(arene)M(L)к1(S)Cl2] where L = L1,… read more here.
Keywords: arene metals; mono dentate; reaction complex; strained complexes ... See more keywords
Synthesis, characterization and chemosensitivity studies of half-sandwich ruthenium, rhodium and iridium complexes containing к and к aroylthiourea ligands
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DOI: 10.1016/j.jorganchem.2018.11.020
Abstract: Abstract The reaction of [(p-cymene)RuCl2]2 and [Cp*MCl2]2 (M = Rh/Ir) metal precursors with aroylthiourea ligands (L1-L3) yielded a series of neutral mono-dentate complexes 1–9. The neutral mono-dentate coordination of aroylthiourea with metals via S atom was confirmed… read more here.
Keywords: mono dentate; synthesis characterization; chemosensitivity; aroylthiourea ligands ... See more keywords