Mono- and Dinuclear Gold(I) Coumarin Complexes: Luminescence Studies and Singlet Oxygen Production.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300020
Abstract: The 4-(thiolmethyl)-7-(diethylamino)-2H-chromen-2-one ligand has been synthesized and used as chromophore in several mono- and dinuclear gold(I) compounds that contain a phosphane at the second coordination position. Four final products were able to obtain in pure… read more here.
Keywords: dinuclear gold; coumarin; mono dinuclear; gold ... See more keywords
Mono- and dinuclear mimics of the [FeFe] hydrogenase enzyme featuring bis(monothiolato) and 1,3,5-triaza-7-phosphaadamantane ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119442
Abstract: Abstract Two new complexes [Fe2(µ-SC6H4CH3-p)2(CO)5(PTA)] 1 and [Fe(κ1-SC6H4CH3-p)2(CO)2(PTA)2] 2 with bis(monothiolato) ligands, resembling the active site of iron hydrogenases have been synthesized and analyzed for proton reduction activity using cyclic voltammetric techniques. The structure and… read more here.
Keywords: mono dinuclear; mimics fefe; dinuclear mimics; bis monothiolato ... See more keywords
Atroposelective Synthesis of C-C Axially Chiral Compounds via Mono- and Dinuclear Vanadium Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00545
Abstract: ConspectusAxially chiral compounds with rotationally constrained σ-bonds that exhibit atropisomerism are lucrative synthetic targets because of their ubiquity in functional materials and natural products. The metal complex-catalyzed enantioselective fabrication of axially chiral scaffolds has been… read more here.
Keywords: vanadium; dinuclear vanadium; reaction; mono dinuclear ... See more keywords
Mono- and dinuclear tetraphosphabutadiene ferrate anions.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04641c
Abstract: Reduction of [CpArFe(μ-Br)]2 (1, CpAr = C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe(η4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42- ligand. The related diiron complex [Na2(THF)5(CpArFe)2(μ,η4:4-P4)] (3)… read more here.
Keywords: mono dinuclear; dinuclear tetraphosphabutadiene; tetraphosphabutadiene ferrate; ferrate anions ... See more keywords
Mono- and dinuclear oxidovanadium(v) complexes of an amine-bis(phenolate) ligand with bromo-peroxidase activities: synthesis, characterization, catalytic, kinetic and computational studies.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04718e
Abstract: The mono- and dinuclear oxidovanadium(v) complexes [VVO(L1)(Cl)] (1) and [L1VVO(μ2-O)VO(L1)] (2) of ONNO donor amine-bis(phenolate) ligand (H2L1) were readily synthesized by the reaction between H2L1 and VCl3.(THF)3 or VO(acac)2 in MeOH or MeCN, respectively, and… read more here.
Keywords: mono dinuclear; amine bis; bis phenolate; oxidovanadium complexes ... See more keywords