Mono- and Dinuclear Gold(I) Coumarin Complexes: Luminescence Studies and Singlet Oxygen Production.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300020
Abstract: The 4-(thiolmethyl)-7-(diethylamino)-2H-chromen-2-one ligand has been synthesized and used as chromophore in several mono- and dinuclear gold(I) compounds that contain a phosphane at the second coordination position. Four final products were able to obtain in pure… read more here.
Keywords: dinuclear gold; coumarin; mono dinuclear; gold ... See more keywords
Mono- and dinuclear mimics of the [FeFe] hydrogenase enzyme featuring bis(monothiolato) and 1,3,5-triaza-7-phosphaadamantane ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119442
Abstract: Abstract Two new complexes [Fe2(µ-SC6H4CH3-p)2(CO)5(PTA)] 1 and [Fe(κ1-SC6H4CH3-p)2(CO)2(PTA)2] 2 with bis(monothiolato) ligands, resembling the active site of iron hydrogenases have been synthesized and analyzed for proton reduction activity using cyclic voltammetric techniques. The structure and… read more here.
Keywords: mono dinuclear; mimics fefe; dinuclear mimics; bis monothiolato ... See more keywords
Atroposelective Synthesis of C-C Axially Chiral Compounds via Mono- and Dinuclear Vanadium Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00545
Abstract: ConspectusAxially chiral compounds with rotationally constrained σ-bonds that exhibit atropisomerism are lucrative synthetic targets because of their ubiquity in functional materials and natural products. The metal complex-catalyzed enantioselective fabrication of axially chiral scaffolds has been… read more here.
Keywords: vanadium; dinuclear vanadium; reaction; mono dinuclear ... See more keywords
Engineering Mono- vs Dinuclear Iron(II)-Active Sites to Steer Liquid Oxygenate Selectivity in Methane Oxidation Pathways Using O2.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c04682
Abstract: The selective oxidation of methane to liquid oxygenates using O2 under mild conditions remains a grand challenge due to the chemical inertness of methane and the competing thermodynamically favored overoxidation. We report the development of… read more here.
Keywords: mono dinuclear; methane; mof 253; selectivity ... See more keywords
Mono- and dinuclear tetraphosphabutadiene ferrate anions.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04641c
Abstract: Reduction of [CpArFe(μ-Br)]2 (1, CpAr = C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe(η4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42- ligand. The related diiron complex [Na2(THF)5(CpArFe)2(μ,η4:4-P4)] (3)… read more here.
Keywords: mono dinuclear; dinuclear tetraphosphabutadiene; tetraphosphabutadiene ferrate; ferrate anions ... See more keywords
Mono- and dinuclear oxidovanadium(v) complexes of an amine-bis(phenolate) ligand with bromo-peroxidase activities: synthesis, characterization, catalytic, kinetic and computational studies.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04718e
Abstract: The mono- and dinuclear oxidovanadium(v) complexes [VVO(L1)(Cl)] (1) and [L1VVO(μ2-O)VO(L1)] (2) of ONNO donor amine-bis(phenolate) ligand (H2L1) were readily synthesized by the reaction between H2L1 and VCl3.(THF)3 or VO(acac)2 in MeOH or MeCN, respectively, and… read more here.
Keywords: mono dinuclear; amine bis; bis phenolate; oxidovanadium complexes ... See more keywords
Impact of nuclear number on SHG and THG performances: A comparative study of chiral mono- and dinuclear TbIII complexes with identical organic ligands
Sign Up to like & getrecommendations! Published in 2025 at "CrystEngComm"
DOI: 10.1039/d5ce00697j
Abstract: The reactions between Tb(dbm)3(H2O) and chiral bis-bidentate N-donor, (+)-2,5-bis(4ʹ,5ʹ-pinene-2ʹ-pyridyl)pyrazine (S-L), in distinct molar ratios of 1:1 and 2:1, yielded two mono- and dinuclear chiral TbIII complexes, [Tb(dbm)3(S-L)]•2H2O (S-Tb-1) and [Tb2(dbm)6(S-L)]•4H2O... read more here.
Keywords: mono dinuclear; impact nuclear; tbiii complexes; nuclear number ... See more keywords
Mono- and dinuclear β-oxo-δ-diiminate (BODDI) based catalysts for the ring-opening polymerization of L-lactide.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt01934f
Abstract: Polyesters such as polylactic acid belong to the most useful biodegradable polymers being able to substitute polyolefins in many applications. In search for potent catalysts based on bio-compatible and non-critical raw materials bimetallic cooperativity has… read more here.
Keywords: diiminate boddi; oxo diiminate; mono dinuclear; opening polymerization ... See more keywords
Crystal structures and photophysical properties of mono- and dinuclear ZnII complexes flanked by triethylammonium
Sign Up to like & getrecommendations! Published in 2024 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989024010302
Abstract: Two new zinc(II) complexes, C21H13Cl2N2O3Zn·C6H16N (ZnOQ) and C20H14Cl4N2O2Zn·2C6H16N (ZnBS), were synthesized and their structures were determined using ESI–MS spectrometry, 1H NMR spectroscopy, and single-crystal X-ray diffraction. read more here.
Keywords: properties mono; dinuclear znii; mono dinuclear; structures photophysical ... See more keywords