Exploration of Homogeneous Ethylene Dimerization Mediated by Tungsten Mono(imido) Complexes
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DOI: 10.1021/acscatal.8b02201
Abstract: In combination with EtAlCl2, complexes {[WCl3(μ-Cl)(N-2,6-iPr2C6H3)]2}, [WCl4(NR)(thf)] (R = Et, iPr, cHx, Ph, 2,6-iPr2C6H3, 4-F-C6H4, and 2,4,6-F3-C6H2), and [WCl2(NR′)(PMe3)3] (R′ = Ph, 2,6-iPr2C6H3) were all productive ethylene dimerization pre-catalysts, giving turnover numbers (TONs) in the… read more here.
Keywords: imido complexes; ethylene dimerization; tungsten mono; mono imido ... See more keywords