Stereoselective Synthesis of Highly Functionalized Cyclohexenes via Strong-Acid-Mediated Endocyclic C-C Bond Cleavage of Monocyclopropanated Cyclopentadienes.
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DOI: 10.1021/acs.orglett.3c00935
Abstract: A stereoselective, solvent- and metal-free endocyclic C-C bond cleavage of monocyclopropanated cyclopentadienes mediated by strong acids was developed, leading to highly functionalized six-membered carbocycles with high stereocontrol. The critical step for this ring-expansion is the… read more here.
Keywords: monocyclopropanated cyclopentadienes; highly functionalized; bond cleavage; cleavage monocyclopropanated ... See more keywords