Combinatorial Nickel-Catalyzed Monofluoroalkylation of Aryl Boronic Acids with Unactivated Fluoroalkyl Iodides.
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DOI: 10.1021/acs.orglett.7b02012
Abstract: A combinatorial nickel-catalyzed cross-coupling between arylboronic acids and unactived 1-fluoro-1-iodoalkanes has been developed, which demonstrated high efficiency, mild conditions, and excellent functional-group compatibility. Readily available nitrogen and phosphine ligands were combined with a nitrogen source,… read more here.
Keywords: monofluoroalkylation aryl; boronic acids; aryl boronic; combinatorial nickel ... See more keywords