Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis
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DOI: 10.1021/acscatal.9b00473
Abstract: Monofluoromethyl (CH2F) radical can be easily generated from a sulfoximine-based precursor (CH2F–S(=O)(=NTs)-Ph) by the action of visible-light metal-free photoredox catalysis with readily accessible 1,4-bis(diphenylamino)naphthalene. The catalyst design based on the high excitation energy (E0,0) and… read more here.
Keywords: monofluoromethylation alkenes; bis diphenylamino; photoredox catalysis; visible light ... See more keywords