Light Directs Monomer Coordination in Catalyst-Free Grignard Photopolymerization.
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DOI: 10.1021/jacs.1c09595
Abstract: π-Conjugated polymers can serve as active layers in flexible and lightweight electronics and are conventionally synthesized by transition-metal-mediated polycondensation at elevated temperatures. We recently reported a photopolymerization of electron-deficient heteroaryl Grignard monomers that enables the… read more here.
Keywords: grignard; monomer coordination; radical anion; catalyst free ... See more keywords