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Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b01297
Abstract: A removable oxime-assisted meta-C-H nitration of arenes is reported. Mechanistic investigations and DFT calculations reveal a new monomeric octahedral ruthenium(II) complex is responsible for the meta-selective nitration. Dioxygen as a cooxidant is crucial for achieving…
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Keywords:
meta nitration;
nitration;
octahedral ruthenium;
ruthenium complex ... See more keywords