Equilibrium and DFT studies of the bi- and mononuclear complexes of 4,4′-bipiperidine with Pd(2-(2-aminoethyl)-1-methylpyrrolidine) 2+ and other biorelevant ligands
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.12.037
Abstract: Pd(AEMP)Cl2 complex, where AEMP1⁄4 2-(2-aminoethyl)-1methylpyrrolidine was synthesized and characterized. The coordination of [Pd(AEMP)(H2O)2]2þ with ligands of biosignificance as DNA constituents, peptides and amino acids having different functional groups was investigated. The present study described the… read more here.
Keywords: mononuclear complexes; aemp h2o; formation; h2o ... See more keywords
Mononuclear complexes of FeII, CoII and CoIII containing imine-based ligands of 8-aminoquinoline and 7-aminoindazole: spin state tuning of FeII complexes in solution
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj01622h
Abstract: Careful selection of the fused ring heterocycle and aldehyde synthons resulted in the spin state tuning of iron(ii) complexes in solution. read more here.
Keywords: mononuclear complexes; complexes feii; complexes solution; spin state ... See more keywords
Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj02104d
Abstract: Two phosphaadamantane-substituted, new mononuclear Mn(I) carbonyl complexes, fac-[Mn(CO)3(κ2-S2NC7H4)(PTA)] 1 and fac-[Mn(CO)3(κ2-SN2C7H5)(PTA)] 2, were synthesized by the aerobic reaction of dinuclear {MnMn} complexes [Mn2(CO)6(µ-S2NC7H4)2] A and [Mn2(CO)6(µ-SN2C7H5)2] B with 1,3,5-triaza-7-phosphaadamantane (PTA) ligand in dichloromethane at room… read more here.
Keywords: triaza phosphaadamantane; featuring donor; mononuclear complexes; complexes featuring ... See more keywords
Zinc(II) mononuclear complexes with Schiff base derivatives of 2-aminofluorene. Synthesis, structural characterization, and optical properties
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1830977
Abstract: Abstract Three Schiff base ligands derived from 2-aminofluorene and 3-methoxysalicylaldehyde (HL1), 3-ethoxysalicylaldehyde (HL2), or 2-formyl-6-hydroxymethyl-p-cresol (HL3) were synthesized and structurally characterized by X-ray diffraction on single crystals. The mononuclear complexes [Zn(L1)2] (4), [Zn(L2)2] (5), [Zn(L3)2]·CHCl3… read more here.
Keywords: mononuclear complexes; zinc mononuclear; base derivatives; complexes schiff ... See more keywords
Crystal structures of two mononuclear complexes of terbium(III) nitrate with the tripodal alcohol 1,1,1-tris(hydroxymethyl)propane
Sign Up to like & getrecommendations! Published in 2017 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989017001116
Abstract: Two new mononuclear complexes of ten- and nine-coordinate terbium(III) were synthesized from Tb(NO3)3·5H2O and the tripodal alcohol 1,1,1-tris(hydroxymethyl)propane (H3 L Et) to be employed as potential building blocks for heterometallic 3d–4f block metal aggregates. read more here.
Keywords: mononuclear complexes; hydroxymethyl propane; tris hydroxymethyl; alcohol tris ... See more keywords
Ligand-Modulated Nuclearity and Geometry in Nickel(II) Hydrazone Complexes: From Mononuclear Complexes to Acetato- and/or Phenoxido-Bridged Clusters
Sign Up to like & getrecommendations! Published in 2023 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms24031909
Abstract: The propensity of 4-hydroxybenzhydrazone-related ligands derived from 3-methoxysalicylaldehyde (H2L3OMe), 4-methoxysalicylaldehyde (H2L4OMe), and salicylaldehyde (H2LH) to act as chelating and/or bridging ligands in Ni(II) complexes was investigated. Three clusters of different nuclearities, [Ni3(L3OMe)2(OAc)2(MeOH)2]∙2MeOH∙MeCN (1∙2MeOH∙MeCN), [Ni2(HL4OMe)(L4OMe)(OAc)(MeOH)2]∙4.7MeOH (2∙4.7MeOH),… read more here.
Keywords: bridged clusters; mononuclear complexes; geometry; acetato phenoxido ... See more keywords