Thermal and Mechanochemical Syntheses of Luminescent Mononuclear Copper(I) Complexes
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700734
Abstract: Mononuclear CuI iodide complexes, [CuI(PPh3)2L] {PPh3 = triphenylphosphine; L = 4-aminoisoquinoline (4-aiq) (2), 5-aminoisoquinoline (5-aiq) (3), and 5-nitroisoquinoline (niq) (4)}, were prepared by three different methods: normally used reactions in the solution state, mechanochemical synthesis,… read more here.
Keywords: thermal mechanochemical; mechanochemical syntheses; syntheses luminescent; luminescent mononuclear ... See more keywords
Mononuclear copper(II) complexes containing chelating ligand of 2-methyl-N-(pyridine-2-yl-methyl)propane-2-amine as chromotropic probes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the Iranian Chemical Society"
DOI: 10.1007/s13738-018-01577-z
Abstract: The synthesis of two mononuclear copper(II) complexes of formula [L2CuX]X where L is a bidentate ligand of N-(pyridin-2-yl-methyl)propane-2-amine and X = Cl, 1 and Br, 2, is reported. Both complexes are fully characterized by elemental analysis, spectroscopic… read more here.
Keywords: methyl propane; copper complexes; propane amine; copper ... See more keywords
Synthesis, crystal structure, magnetic properties and DFT calculations of a mononuclear copper(II) complex: Relevance of halogen bonding for magnetic interaction
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.06.033
Abstract: Abstract The synthesis, crystal structure, magnetic properties and DFT calculations of a new mononuclear copper(II) complex containing a pyrazole-based ligand are reported. In the crystal structure of the [CuCl2L2] complex (L = Ethyl 5-amino-1-(4-methoxyphenyl)-1H-pyrazole-4-carboxylate), a network of… read more here.
Keywords: crystal structure; dft calculations; synthesis crystal; mononuclear copper ... See more keywords
Influence of the secondary coordination sphere on the physical properties of mononuclear copper(II) complexes and their catalytic activity on the oxidation of 3,5-di-tert-butylcatechol
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2017.11.020
Abstract: Abstract Three mononuclear copper(II) complexes (C1–C3) containing the ligand 2-(2-aminomethyl)pyridine (aep) and some modifications of it were designed to get insights on the influence of pendant second sphere groups (thiophene and benzene) on their physicochemical… read more here.
Keywords: copper complexes; tert butylcatechol; copper; coordination sphere ... See more keywords
Mononuclear Copper Complexes with Tridentate Tris(N-heterocyclic carbene): Synthesis and Catalysis of Alkyne–Azide Cycloaddition
Sign Up to like & getrecommendations! Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00457
Abstract: Mononuclear copper complexes modified with tridentate tris(N-heterocyclic carbene) (triscarbene) ligands are synthesized. The structures of the copper–triscarbene complexes are characterized using ... read more here.
Keywords: copper complexes; tris heterocyclic; mononuclear copper; tridentate tris ... See more keywords
Unusual slow magnetic relaxation in a mononuclear copper(II) complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00023g
Abstract: A hexacoordinate Cu(II) complex with the {CuO4O'N} donor set shows an intermolecular π-π stacking owing to which a 1D-chain structure is formed. The DC magnetic data at low temperature are consistent with the Curie law.… read more here.
Keywords: relaxation mononuclear; unusual slow; magnetic relaxation; relaxation ... See more keywords
New mononuclear copper(II) complexes from β-diketone and β-keto ester N-donor heterocyclic ligands: structure, bioactivity, and molecular simulation studies
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1447668
Abstract: Abstract Four new mononuclear copper(II) complexes with methyl acetoacetate and benzoylacetone in the presence of 1,10-phenanthroline and 2,2′-bipyridine were synthesized and characterized by elemental analyses, FT-IR, and UV–Vis spectroscopy. The molecular structures of complexes [Cu(MAA)(bpy)(ClO4)]… read more here.
Keywords: copper complexes; new mononuclear; mononuclear copper; structure ... See more keywords
Mononuclear copper(I) complexes with triphenylphosphine and N,N′-disubstituted thioureas: synthesis, characterization, and biological evaluation
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1538504
Abstract: Abstract Twelve new complexes, of the general formula CuCl(TPP)2Tu1–12 (Tu = thiourea), were synthesized by the reaction of CuCl(TPP)3 (TPP = triphenylphosphine) and various N,N′-disubstituted thioureas. The structures of the synthesized complexes were characterized by different techniques such as… read more here.
Keywords: copper complexes; copper; disubstituted thioureas; mononuclear copper ... See more keywords
Synthesis, characterization and nucleic acid binding studies of mononuclear copper(II) complexes derived from azo containing O, O donor ligands
Sign Up to like & getrecommendations! Published in 2018 at "Nucleosides, Nucleotides and Nucleic Acids"
DOI: 10.1080/15257770.2018.1508694
Abstract: Abstract Azo linked salicyldehyde and a new 2-hydroxy acetophenone based ligands (HL1 and HL2) with their copper(II) complexes [Cu(L1)2] (1) and [Cu(L2)2] (2) were synthesized and characterized by spectroscopic methods such as 1H, 13C NMR,… read more here.
Keywords: copper complexes; copper; mononuclear copper; binding studies ... See more keywords
Crystal structure of a mononuclear copper(II) complex with 2-methoxy-N,N-bis(quinolin-2-ylmethyl)ethylamine (DQMEA)
Sign Up to like & getrecommendations! Published in 2018 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989018010319
Abstract: The crystal structure of [Cu(DQMEA)(CH3CN)](ClO4)2 (DQMEA = N,N-bis(2-quinolylmethyl)methoxyethylamine) has been determined. The structure reveals a five-coordinate CuII center with a distorted square-pyramidal geometry. read more here.
Keywords: crystal structure; mononuclear copper; bis; structure ... See more keywords
Synthesis, Crystal Structures and Urease Inhibition of Mononuclear Copper(II) and Nickel(II) Complexes with Schiff Base Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Acta chimica Slovenica"
DOI: 10.17344/acsi.2022.7513
Abstract: Three mononuclear copper(II) and nickel(II) complexes, [Cu(L1)(NCS)(CH3OH)] (1), [Cu(L2)(NCS)] (2) and [Ni(L2)(N3)] (3), where L1 and L2 are the monoanionic forms of the Schiff bases N'-(pyridin-2-ylmethylene)picolinohydrazide (HL1) and 4-methyl-2-(((pyridin-2-ylmethyl)imino)methyl)phenol (HL2), have been prepared and characterized… read more here.
Keywords: nickel complexes; base ligands; mononuclear copper; copper nickel ... See more keywords