Aligning π-Extended π-Deficient Ligands to Afford Submicrosecond Phosphorescence Radiative Decay Time of Mononuclear Ir(III) Complexes.
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DOI: 10.1021/acs.inorgchem.2c03403
Abstract: Herein, we report a profound investigation of the photophysical properties of three mononuclear Ir(III) complexes fac-Ir(dppm)3 (Hdppm-4,6-bis(4-(tert-butyl)phenyl)pyrimidine), Ir(dppm)2(acac) (acac-acetylacetonate), and Ir(ppy)2(acac) (Hppy-phenylpyridine). The heteroleptic Ir(dppm)2(acac) is found to emit with efficiency above 80% and feature… read more here.
Keywords: dppm acac; phosphorescence; mononuclear iii; iii complexes ... See more keywords