Articles with "mononuclear lanthanide" as a keyword



Luminescent and magnetic properties of mononuclear lanthanide thiocyanates with terpyridine as auxiliary ligand

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Published in 2019 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2018.11.006

Abstract: Abstract Novel mononuclear lanthanide thiocyanates with 2,2′;6′,2″-terpyridine (terpy), namely isomorphic complexes [Ln(terpy)2(NCS)3] (Ln = Y, Eu, Tb and Dy) were prepared and studied. The effective luminescence sensitization of the Eu, Tb and Dy ions owing to the… read more here.

Keywords: luminescent magnetic; lanthanide thiocyanates; mononuclear lanthanide; thiocyanates terpyridine ... See more keywords

C-O Bond Activation in Mononuclear Lanthanide Oxocarbonyl Complexes OLn(η2-CO) (Ln = La, Ce, Pr, and Nd).

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03452

Abstract: Fundamental investigation of metal-CO interactions is of great importance for the development of high-performance catalysts to CO activation. Herein, a series of side-on bonded mononuclear lanthanide (Ln) oxocarbonyl complexes OLn(η2-CO) (Ln = La, Ce, Pr,… read more here.

Keywords: mononuclear lanthanide; chemistry; oxocarbonyl complexes; lanthanide oxocarbonyl ... See more keywords

Near-infrared emissive mononuclear lanthanide(III) complexes based on chiral Schiff base ligands: synthesis, crystal structure, luminescence, and magnetic properties.

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Published in 2025 at "Dalton transactions"

DOI: 10.1039/d5dt01071c

Abstract: In this study, novel chiral mononuclear complexes (teaH)[Ln((R,R)-dnsalcd)2] (Ln = Nd3+ (1), Ho3+ (2), Er3+ (3), Yb3+ (4), and Gd3+ (5)), where teaH = triethylammonium and (R,R)-H2dnsalcd = (R,R)-N,N'-bis(3,5-dinitrosalicylidene)-1,2-cyclohexanediamine, were synthesized and characterized. Their structural… read more here.

Keywords: emissive mononuclear; infrared emissive; mononuclear lanthanide; magnetic properties ... See more keywords