Synthesis of a mononuclear magnesium bis(alkoxide) complex and its reactivity in the ring-opening copolymerization of cyclic anhydrides with epoxides.
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DOI: 10.1039/c9dt04274a
Abstract: Synthesis of a new mononuclear magnesium complex with a bulky bis(alkoxide) ligand environment and its reactivity in ring-opening polymerization (ROP) and ring-opening copolymerization (ROCOP) are reported. Reaction of n-butyl-sec-butylmagnesium with two equivalents of HOR (HOR… read more here.
Keywords: ring opening; bis alkoxide; copolymerization; mononuclear magnesium ... See more keywords