Computational Electrochemistry as a Reliable Probe of Experimentally Elusive Mononuclear Nonheme Iron Species
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b02698
Abstract: Despite the growing number of reported FeIVO complexes, an unambiguous experimental characterization of their redox properties, such as one-electron reduction potentials, remains a challenging task. To this aim, we describe an efficient and straightforward theoretical… read more here.
Keywords: mononuclear nonheme; methodology; electrochemistry; nonheme iron ... See more keywords
Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b05274
Abstract: The activation of dioxygen by FeII(Me3TACN)(S2SiMe2) (1) is reported. Reaction of 1 with O2 at -135 °C in 2-MeTHF generates a thiolate-ligated (peroxo)diiron complex FeIII2(O2)(Me3TACN)2(S2SiMe2)2 (2) that was characterized by UV-vis (λmax = 300, 390,… read more here.
Keywords: mononuclear nonheme; activation dioxygen; me3tacn s2sime2; dioxygen ... See more keywords