Articles with "mononuclear ruthenium" as a keyword



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Structural, spectral, DFT and biological studies on macrocyclic mononuclear ruthenium (II) complexes

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Published in 2017 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2017.06.132

Abstract: Abstract Macrocyclic mononuclear ruthenium (II) complexes have been synthesized by condensation method [Ru (L1, L2, L3) Cl 2 ] L 1  = (C 36 H 31 N 9 ), L 2 = (C 42 H… read more here.

Keywords: ruthenium; mononuclear ruthenium; dft; macrocyclic mononuclear ... See more keywords
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Distinctive Aspects in Aquation, Proton-Coupled Redox, and Photoisomerization Reactions between Geometric Isomers of Mononuclear Ruthenium Complexes with a Large-π-Conjugated Tetradentate Ligand.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01937

Abstract: Geometric isomers of mononuclear ruthenium(II) complexes, distal-/proximal-[Ru(tpy)(dpda)Cl]+ (d-/p-RuCl, tpy = 2,2':6',2″-terpyridine, dpda = 2,7-bis(2-pyridyl)-1,8-diazaanthracene), were newly synthesized to comprehensively investigate the geometric and electronic structures and distinctive aspects in various reactions between isomers. The ultraviolet… read more here.

Keywords: ruthenium complexes; mononuclear ruthenium; dpda; geometric isomers ... See more keywords
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Mononuclear Ruthenium-Based Water Oxidation Catalyst Supported by Anionic, Redox-Non-Innocent Ligand: Heterometallic O-O Bond Formation via Radical Coupling Pathway.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.9b03258

Abstract: Cerium(IV)-driven water oxidation catalysis mediated by a mononuclear ruthenium(III) complex, [Ru(L)(pic)3] (H3L = 2,2'-iminodibenzoic acid, pic = 4-methylpyridine), has been demonstrated in this work. The mechanistic details of water oxidation have been investigated by the… read more here.

Keywords: water; ligand; water oxidation; mononuclear ruthenium ... See more keywords

Mononuclear ruthenium(ii) theranostic complexes that function as broad-spectrum antimicrobials in therapeutically resistant pathogens through interaction with DNA†

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Published in 2020 at "Chemical Science"

DOI: 10.1039/d0sc03410j

Abstract: Six luminescent, mononuclear ruthenium(ii) complexes based on the tetrapyridophenazine (tpphz) and dipyridophenazine (dppz) ligands are reported. The therapeutic activities of the complexes against Gram-negative bacteria (E. coli, A. baumannii, P. aeruginosa) and Gram-positive bacteria (E.… read more here.

Keywords: gram positive; mononuclear ruthenium; dna; gram ... See more keywords