X-ray characterization, spectroscopic, DFT calculations and Hirshfeld surface analysis of two 3-D supramolecular mononuclear zinc(II) and trinuclear copper(II) complexes
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DOI: 10.1016/j.poly.2018.10.052
Abstract: Abstract Two three-dimensional mononuclear zinc(II) and trinuclear copper(II) complexes, [Zn(L2)2]·2CH3OH (1) and [Cu(L2)]3·CH3OH (2) (HL2 = 1-(2-{[(E)-3-bromo-5-chloro-2-hydroxybenzylidene]amino}phenyl)ethanone oxime), were synthesized via complexation of metal salts with based ligand HL1 (2-(3-bromo-5-chloro-2-hydroxyphenyl)-4-methyl-1,2-dihydroquinazoline 3-oxide, H is the deprotonatable hydrogen) originally.… read more here.
Keywords: trinuclear copper; copper complexes; zinc trinuclear; dft calculations ... See more keywords
Two new mononuclear zinc(II) and cadmium(II) coordination polymers based on 4-(3-pyridyl)-2H-1,2,3-triazole: Syntheses, structures, theoretical and fluorescent properties
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DOI: 10.1016/j.poly.2019.03.028
Abstract: Abstract Two new d10 metal coordination polymers (CPs), [Zn(L)NO3]n (1) and [Cd(L)I2]n (2) (L = 4-(3-Pyridyl)-2H-1,2,3-triazole), have been designed and synthesized from ZnII/CdII ions and the rigid L ligand. The CPs 1 and 2 have been structurally… read more here.
Keywords: two new; new mononuclear; coordination polymers; mononuclear zinc ... See more keywords
Hydrothermal Preparation, Crystal Structure, Photoluminescence and UV-Visible Diffuse Reflectance Spectroscopic Properties of a Novel Mononuclear Zinc Complex.
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DOI: 10.17344/acsi.2019.5532
Abstract: A novel mononuclear zinc complex [ZnL(Phen)(H2O)]·H2O containing the mixed ligands of Phen (Phen = 1,10-phenanthroline) and 3-hydroxy-2-methylquinoline-4-carboxylic acid (HL) was prepared by hydrothermal synthesis and its crystal structure was characterized by X-ray single-crystal diffraction method.… read more here.
Keywords: crystal; novel mononuclear; structure; crystal structure ... See more keywords