Electrophilic d0 Cations of Group 4 Metals (M = Ti, Zr, Hf) Derived from Monopentafulvene Complexes: Direct Formation of Tridentate Cp,O,P-Ligands
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DOI: 10.1021/acs.organomet.8b00088
Abstract: The reactions of the monopentafulvene complexes Ti1a and Ti1b with the general formula [Cp*Ti(Cl)(π-η5:σ-η1-C5H4═CR2)] (R = p-tolyl (Ti1a); CR2 = adamantylidene (Ti1b)) with the bidentate P,O-ligand precursor L1, featuring a diphenylphosphine and a hydroxyl functional… read more here.
Keywords: monopentafulvene complexes; group; reaction; group metals ... See more keywords