A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions.
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DOI: 10.1021/jacs.7b03716
Abstract: Kinetic and mechanistic studies of the desymmetrization of benzhydrylamine using Pd/monoprotected amino acid ligands (Pd/MPAA) via C-H functionalization with molecular iodine provide mechanistic insight into the rate-determining step and the oxidation state of Pd in… read more here.
Keywords: acid ligands; amino acid; monoprotected amino; role catalytic ... See more keywords