Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight.
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DOI: 10.1039/c7cc03486e
Abstract: Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480)… read more here.
Keywords: monoradical containing; iii complexes; four coordinate; cleavage ... See more keywords