Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01554
Abstract: The heterometallic complex [MoReCp(μ-PR*)(CO)6] (3) was prepared in 60% overall yield from syn-[MoCp(PHR*)(CO)2] via a three-step procedure involving complexes syn-[MoCp(PClR*)(CO)2] and [MoReCp(μ-PR*)(CO)7] as intermediate species (R* = 2,4,6-C6H2tBu3). The PR* ligand in 3 displays a… read more here.
Keywords: morecp; efficient synthesis; bridged complex; phosphinidene ... See more keywords
Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex.
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DOI: 10.1021/acs.inorgchem.7b02879
Abstract: The title compound was prepared upon irradiation of acetonitrile solutions of the readily available hexacarbonyl [MoReCp(μ-H)(μ-PCy2)(CO)6]. The acetonitrile ligand in this compound could be replaced easily by donor molecules or displaced upon two-electron reduction. In… read more here.
Keywords: morecp; morecp pcy2; adduct morecp; pcy2 ncme ... See more keywords