Multicenter bonding in s-block metals: An insight from theory
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2019.112606
Abstract: Abstract Multicenter bonding, one of the common phenomenon in p-block as well as d-block metals, is a rare phenomenon in s-block metals. Very few examples, if not none, are there in the literature. Herein, we… read more here.
Keywords: multicenter; block metals; multicenter bonding; metals insight ... See more keywords
The nature of the multicenter bonding in π-[TCNE]22− dimer: 4c/2e, 12c/2e, or 20c/2e?
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra09023d
Abstract: The dianion dimer of tetracyanoethylene (TCNE), π-[TCNE]22−, represents an unusual class of organic compounds, that possess exceptionally long C–C bonding interactions (∼2.96 A). It is twice that of conventional C–C bonds but shorter than the… read more here.
Keywords: bonding tcne; dimer; multicenter bonding; nature multicenter ... See more keywords