Iridium-catalyzed chemoselective asymmetric hydrogenation of conjugated enones with ferrocene-based multidentate phosphine ligands.
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DOI: 10.1039/d2cc01583h
Abstract: A series of novel and readily prepared ferrocene-based multidentate phosphine ligands (f-PNNO) have been developed and successfully used in iridium-catalyzed enantioselective 1,2-reduction of α,β-unsaturated ketones, delivering chiral allylic alcohols in high yields and high enantioselectivities… read more here.
Keywords: multidentate phosphine; asymmetric hydrogenation; iridium catalyzed; ferrocene based ... See more keywords