Peroxidase versus Peroxygenase Activity: Substrate Substituent Effects as Modulators of Enzyme Function in the Multifunctional Catalytic Globin Dehaloperoxidase.
Sign Up to like & getrecommendations! Published in 2018 at "Biochemistry"
DOI: 10.1021/acs.biochem.8b00540
Abstract: The dehaloperoxidase-hemoglobin (DHP) from the terebellid polychaete Amphitrite ornata is a multifunctional hemoprotein that catalyzes the oxidation of a wide variety of substrates, including halo/nitrophenols, haloindoles, and pyrroles, via peroxidase and/or peroxygenase mechanisms. To probe… read more here.
Keywords: peroxidase; multifunctional catalytic; substituent effects; substrate substituent ... See more keywords
A new inhibition mechanism in the multifunctional catalytic hemoglobin dehaloperoxidase as revealed by the DHP A(V59W) mutant: A spectroscopic and crystallographic study
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Porphyrins and Phthalocyanines"
DOI: 10.1142/s1088424621500826
Abstract: As multifunctional catalytic hemoglobins, dehaloperoxidase isoenzymes A and B (DHP A and B) are among the most versatile hemoproteins in terms of activities displayed. The ability of DHP to bind over twenty different substrates in… read more here.
Keywords: dhp v59w; v59w; distal pocket; mechanism ... See more keywords
Copper–Zirconia Catalysts: Powerful Multifunctional Catalytic Tools to Approach Sustainable Processes
Sign Up to like & getrecommendations! Published in 2020 at "Catalysts"
DOI: 10.3390/catal10020168
Abstract: Copper–zirconia catalysts find many applications in different reactions owing to their unique surface properties and relatively easy manufacture. The so-called methanol economy, which includes the CO2 and CO valorization and the hydrogen production, and the… read more here.
Keywords: zirconia catalysts; catalysts powerful; multifunctional catalytic; copper zirconia ... See more keywords
Efficient Multifunctional Catalytic and Sensing Properties of Synthesized Ruthenium Oxide Nanoparticles
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DOI: 10.3390/catal10070780
Abstract: Ruthenium oxide is one of the most active electrocatalyst for oxygen evolution (OER) and oxygen reduction reaction (ORR). Herein, we report simple wet chemical route to synthesize RuO2 nanoparticles at controlled temperature. The structural, morphological… read more here.
Keywords: efficient multifunctional; catalytic sensing; multifunctional catalytic; ruo2 nanoparticles ... See more keywords