Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands.
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DOI: 10.1021/acs.inorgchem.8b01422
Abstract: Phosphabenzamidine [mes-NH-C(Ph)═P-mes) (1) and phosphaformamidine (mes-NH-CH═P-mes) (4) ligands have been synthesized and characterized. The conjugate bases of 1 and 4 coordinate by each bridging three Cu(I) ions, forming hexa- and tetranuclear clusters Cu6[mes-N═C(Ph)-P-mes]3Cl4Li(THF)2 (3) and… read more here.
Keywords: coordination mode; multinuclear clusters; clusters featuring; mes mes ... See more keywords