Tin(IV) fluoride complexes with neutral phosphine coordination and comparisons with hard N- and O-donor ligands.
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DOI: 10.1039/d1dt02948g
Abstract: The reactions of trans-[SnF4(PMe3)2] with one, two or three equivalents of Me3SiO3SCF3 (TMSOTF), respectively, in anhydrous CH2Cl2 form six-coordinate [SnF4-n(PMe3)2(OTf)n] (n = 1-3), which have been characterised by microanalysis, IR and multinuclear NMR (1H, 19F{1H},… read more here.
Keywords: pme3 otf; otf; multinuclear nmr; spectroscopy ... See more keywords