Desolvation Synergy of Multiple H/Li‐Bonds on an Iron‐Dextran‐Based Catalyst Stimulates Lithium–Sulfur Cascade Catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202207074
Abstract: Traditional lithium–sulfur battery catalysts are still facing substantial challenges in solving sulfur redox reactions, which involve multistep electron transfer and multiphase transformations. Here, inspired by the combination of iron dextran (INFeD) and ascorbic acid (VC)… read more here.
Keywords: multiple bonds; lithium sulfur; iron dextran; sulfur ... See more keywords
Electrofluorochromic and electrochromic bifunctional polymers with dual-state emission via introducing multiple C—H···π bonds
Sign Up to like & getrecommendations! Published in 2018 at "Organic Electronics"
DOI: 10.1016/j.orgel.2018.08.042
Abstract: Abstract Novel polythiophene derivatives containing trans-stilbene and fumaronitrile groups have been designed and synthesized. These polymers emit intense fluorescence in both solution and film states, attributing to the restriction of intramolecular rotation caused by multiple… read more here.
Keywords: state; electrochromic bifunctional; bifunctional polymers; multiple bonds ... See more keywords
Lewis acid mediated Michael addition of non-aromatic multiple C–C bonds to α,β-unsaturated dicarbonyl compounds
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2021.153272
Abstract: Abstract Michael addition is widely used in organic synthesis, being one of the key methods for the formation of C–C and C–X bonds. This mini-review is focused on the addition reactions of non-activated and non-aromatic… read more here.
Keywords: non aromatic; multiple bonds; addition; bonds unsaturated ... See more keywords
Activation of C-F bonds α to C-C multiple bonds.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05108a
Abstract: C-F bond activation has drawn a lot of attention in the past, and the case of C(sp3)-F bonds is particularly interesting as those are the strongest single bonds carbon makes with any other element. This… read more here.
Keywords: bonds multiple; multiple bonds; activation bonds; activation ... See more keywords
The interplay of carbophilic activation and Au(I)/Au(III) catalysis: an emerging technique for 1,2-difunctionalization of C-C multiple bonds.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Society reviews"
DOI: 10.1039/d0cs00700e
Abstract: Gold complexes have emerged as the catalysts of choice for various functionalization reactions of C-C multiple bonds due to their inherent carbophilic nature. In a parallel space, efforts to realize less accessible cross-coupling reactivity have… read more here.
Keywords: activation iii; iii catalysis; carbophilic activation; catalysis ... See more keywords
Carbon–chalcogen bond formation initiated by [Al(NONDipp)(E)]− anions containing Al–E{16} (E{16} = S, Se) multiple bonds
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DOI: 10.1039/d2sc01064j
Abstract: Multiply-bonded main group metal compounds are of interest as a new class of reactive species able to activate and functionalize a wide range of substrates. The aluminium sulfido compound K[Al(NONDipp)(S)] (NONDipp = [O(SiMe2NDipp)2]2−, Dipp =… read more here.
Keywords: multiple bonds; nondipp anions; bond formation; containing multiple ... See more keywords
Generation of Active Ruthenium Catalysts for Hydroarylation of C–C Multiple Bonds from Isolated Ru(IV)=O Species Supported on CeO2
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DOI: 10.1246/bcsj.20180144
Abstract: This paper reports that the treatment of Ru/CeO2 with PPh3 and HCHO in 2-methoxyalcohol was an efficient way to generate the catalytically active Ru species for hydroarylation of C-C multiple bonds. A variety of alkenes… read more here.
Keywords: hydroarylation multiple; ruthenium catalysts; multiple bonds; active ruthenium ... See more keywords