Cu-Catalyzed Aerobic Oxidative Sulfuration/Annulation Approach to Thiazoles via Multiple Csp3-H Bond Cleavage.
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DOI: 10.1021/acs.orglett.8b00840
Abstract: A novel and practical Cu-catalyzed aerobic oxidative synthesis of thiazoles was developed. This chemistry for the first time achieved thiazole construction from simple aldehydes, amines, and element sulfur through multiple Csp3-H bond cleavage processes. Molecular… read more here.
Keywords: sulfuration annulation; multiple csp3; bond cleavage; csp3 bond ... See more keywords