Boron-heteroelement (B–E; E = Al, C, Si, Ge, N, P, As, Bi, O, S, Se, Te) multiply bonded compounds: Recent advances
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DOI: 10.1016/j.ccr.2020.213647
Abstract: Abstract Multiple bonding involving the heavier main-group elements has been of great interest for a long time. This interest stems from the structure-bonding-reactivity aspects of these unusual compounds. Despite many initial failures, success in this… read more here.
Keywords: heteroelement multiply; multiply bonded; boron heteroelement; compounds recent ... See more keywords
Low-Valent, Multiply Bonded, Trigonal-Planar Sb Complex: Rational Syntheses, Dual Acidic/Basic Properties, and Unexpected Semiconducting Characteristics.
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DOI: 10.1021/acs.inorgchem.0c02820
Abstract: A 4-center, 6π-conjugated, multiply bonded trigonal-planar complex, [Sb{Cr(CO)5}3]- (1), was synthesized via the hydride abstraction of [HSb{Cr(CO)5}3]2- (1-H) with HBF4·H2O, with the release of high yields of H2. The oxidation state of the Sb atom… read more here.
Keywords: planar complex; low valent; trigonal planar; multiply bonded ... See more keywords