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Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213647
Abstract: Abstract Multiple bonding involving the heavier main-group elements has been of great interest for a long time. This interest stems from the structure-bonding-reactivity aspects of these unusual compounds. Despite many initial failures, success in this…
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Keywords:
heteroelement multiply;
multiply bonded;
boron heteroelement;
compounds recent ... See more keywords
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Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02820
Abstract: A 4-center, 6π-conjugated, multiply bonded trigonal-planar complex, [Sb{Cr(CO)5}3]- (1), was synthesized via the hydride abstraction of [HSb{Cr(CO)5}3]2- (1-H) with HBF4·H2O, with the release of high yields of H2. The oxidation state of the Sb atom…
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Keywords:
planar complex;
low valent;
trigonal planar;
multiply bonded ... See more keywords