Functionality proportion and corresponding stability study of multivariate metal-organic frameworks
Sign Up to like & getrecommendations! Published in 2017 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2017.12.026
Abstract: Abstract Multivariate metal-organic frameworks (MTV-MOFs) with different ratios of terephthalate (BDC) linker and amino-benzenedicarboxylate (BDC-NH 2 ) linker were synthesized through both direct synthesis from linker mixture and linker exchange of activated single-linker MOFs. Functionality… read more here.
Keywords: functionality; multivariate metal; metal organic; linker ... See more keywords
Broadly Tunable Atmospheric Water Harvesting in Multivariate Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09756
Abstract: Development of multivariate metal-organic frameworks (MOFs) as derivatives of the state-of-art water-harvesting material MOF-303 {[Al(OH)(PZDC)], where PZDC2- is 1H-pyrazole-3,5-dicarboxylate} was shown to be a powerful tool to generate efficient water sorbents tailored to a given… read more here.
Keywords: organic frameworks; water; multivariate metal; metal organic ... See more keywords
Effect of Spatial Heterogeneity on the Unusual Uptake Behavior of Multivariate-Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12207
Abstract: The uniqueness of multivariate metal-organic frameworks (MTV-MOFs) has been widely explored to discover their unknown opportunities. While mesoscopic apportionments have been studied, macroscopic heterogeneity and its spatial effects remain unexplored in MTV-MOFs. In this study,… read more here.
Keywords: heterogeneity; organic frameworks; mtv mofs; metal organic ... See more keywords
Modulating Charges of Dual Sites in Multivariate Metal-Organic Frameworks for Boosting Selective Aerobic Epoxidation of Alkenes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00460
Abstract: Selective aerobic epoxidation of alkenes without any additives is of great industrial importance but still challenging because the competitive side reactions including C═C bond cleavage and isomerization are difficult to avoid. Here, we show fabricating… read more here.
Keywords: selective aerobic; epoxidation alkenes; epoxidation; multivariate metal ... See more keywords