Ultrafine Silver Nanoparticle Encapsulated Porous Molecular Traps for Discriminative Photoelectrochemical Detection of Mustard Gas Simulants by Synergistic Size‐Exclusion and Site‐Specific Recognition
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202202287
Abstract: The rapid, discriminative, and portable detection of highly toxic chemical warfare agents is extremely important for response to public security emergencies but remains a challenge. One plausible solution involves the integration of porous molecular traps… read more here.
Keywords: mustard gas; molecular traps; gas simulants; synergistic size ... See more keywords
Ultrafast Photocatalytic Detoxification of Mustard Gas Simulants by a Mesoporous Metal-Organic Framework with Dangling Porphyrin Molecules.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301050
Abstract: Developing effective catalysts to degrade chemical warfare agents is of great significance. Herein, a mesoporous MIL-101(Cr) composite material dangled with porphyrin molecules (denote as TCPP@MIL-101(Cr), TCPP = tetra(4-carboxyphenyl)porphyrin) is reported, which can be used as… read more here.
Keywords: mustard gas; tcpp mil; gas simulants; detoxification mustard ... See more keywords
Unveiling Ru(bpy)3 2+-Encapsulated Zeolite Y as Photocatalyst: Harnessing Photocatalytic Singlet Oxygen Generation for Mustard Gas Simulant Detoxification.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202405559
Abstract: This study explores the encapsulation of Ru(bpy)3 2+ within Zeolite Y (ZY) to improve photocatalytic singlet oxygen generation for the degradation of a mustard gas simulant, namely 2-chloroethyl ethyl sulfide (CEES). Mustard gas simulants are… read more here.
Keywords: bpy; mustard gas; oxygen; singlet oxygen ... See more keywords
Zinc peroxide nanoparticles: Surface, chemical and optical properties and the effect of thermal treatment on the detoxification of mustard gas
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2017.12.068
Abstract: Abstract Highly porous zinc peroxide nanoparticles were synthesized at ambient conditions following a one-pot wet precipitation method. Subsamples were calcined at various temperatures up to 400 °C. The structural, morphological, optical and chemical features were evaluated… read more here.
Keywords: peroxide nanoparticles; mustard gas; detoxification; zinc peroxide ... See more keywords
Polyoxometalate hybrid catalyst for detection and photodecomposition of mustard gas surrogate vapors
Sign Up to like & getrecommendations! Published in 2019 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2018.10.167
Abstract: Abstract The polyoxometalate hybrid (POM-h) nanorods were synthesized and tested as reactive adsorbents of the vapors of mustard gas surrogates, and in particular against 2-chloroethyl ethyl sulfide (CEES) and ethylethyl sulfide (EES). They were found… read more here.
Keywords: photo; polyoxometalate hybrid; surrogate vapors; mustard gas ... See more keywords
Harmony of computational quantum chemistry and experimental chemistry: Comprehensive DFT studies, microsynthesis, and characterization of mustard gas polysulfide analogues
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.01.067
Abstract: Abstract After microsynthesis, structures of mustard gas polysulfide analogues were characterized using electron impact (EI) mass spectrometry. General EI fragmentation pathways for such compounds are proposed. The structure of sulfur mustard (HD) and its two… read more here.
Keywords: mustard gas; polysulfide analogues; chemistry; gas polysulfide ... See more keywords
Ocular toxicity of mustard gas: a concise review.
Sign Up to like & getrecommendations! Published in 2021 at "Toxicology letters"
DOI: 10.1016/j.toxlet.2021.02.007
Abstract: Sulfur mustard (SM) is a chemical warfare agent that has been used throughout recent history and remains a threat today. Exposed soldiers and civilians experience a variety of symptoms primarily in the respiratory system, skin,… read more here.
Keywords: mustard gas; mustard; review; ocular toxicity ... See more keywords
Selective and efficient detoxification of sulfur mustard gas analogues with H2O2 using bioinspired Mo and W dithiolene catalysts.
Sign Up to like & getrecommendations! Published in 2024 at "ACS catalysis"
DOI: 10.1021/acscatal.4c01979
Abstract: Efficient and selective decomposition of chemical warfare agents (CWAs) is required to cope with threats from accidental or intentional releases from stockpiles. One of the most stockpiled CWAs is sulfur mustard (SM) gas. The most… read more here.
Keywords: mustard; sulfur mustard; dithiolene catalysts; mustard gas ... See more keywords
A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light
Sign Up to like & getrecommendations! Published in 2020 at "Green Chemistry"
DOI: 10.1039/d0gc01142h
Abstract: A low footprint, mobile, robust and frugal chemical neutralization technology is reported for the oxidative neutralization of a mustard gas simulant. It relies on the inherent properties of a highly engineered continuous flow setup and… read more here.
Keywords: mustard gas; neutralization; gas simulant;
Mustard Gas–Induced Ocular Surface Disorders: An Update on the Pathogenesis, Clinical Manifestations, and Management
Sign Up to like & getrecommendations! Published in 2022 at "Cornea"
DOI: 10.1097/ico.0000000000003182
Abstract: Purpose: Mustard gas (MG) is a potent blistering and alkylating agent that has been used for military and terrorism purposes. Ocular surface injuries are common after exposure to MG. This review provides an update on… read more here.
Keywords: mustard gas; management; surface; ocular surface ... See more keywords
Pulmonary rehabilitation in patients with mustard gas lung disease: a study protocol for a randomized controlled trial
Sign Up to like & getrecommendations! Published in 2019 at "Trials"
DOI: 10.1186/s13063-019-3180-3
Abstract: BackgroundMore than 60,000 people have health problems due to chemical weapons exposure during the Iran–Iraq war. Respiratory consequences of mustard gas exposure are common and disabling; medical interventions have limited effect. Patients complain of cough,… read more here.
Keywords: pulmonary rehabilitation; trial; mustard gas; disease ... See more keywords