Significantly increased stability of donor-acceptor molecular complexes under heterogeneous conditions: Synthesis, characterization and photosensitizing activity of a nano-structured porphyrin-Lewis acid adduct.
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DOI: 10.1021/acsami.0c13598
Abstract: While the BF3 complexes of meso-tetra(aryl)porphyrins are readily decomposed into their components under aqueous conditions, immobilization of meso-tetrakis(N-methylpyridinium-4-yl)porphyrin (H2TMPyP) on a nanosized polymer (sodium salt of amberlyst 15, nanoAmbSO3Na) formed a water stable BF3 complex… read more here.
Keywords: bf3; nanoambso3 h2tmpyp; molecular complexes; spectroscopy ... See more keywords