Quantum chemical studies of mercaptan gas detection with calcium oxide nanocluster
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-021-04959-y
Abstract: The electronic sensitivity and adsorption behavior for mercaptan natural gas of a Ca12O12 nanocluster were studied via ab initio computations. To be more specific, to fully grasp the influence of mercaptan molecules on the chemical… read more here.
Keywords: quantum chemical; ca12o12 nanocluster; chemical studies; gas ... See more keywords
Interaction of α-Cyano-4-hydroxycinnamic Acid Drug with Inorganic BN Nanocluster: A Density Functional Study
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-018-0778-y
Abstract: We inspected the possibility of using a synthesized boron nitride nanocluster (B12N12) as a potential chemical sensor for anticancer α-cyano-4-hydroxycinnamic acid (CHC) drug by performing density functional theory calculations. It was found that CHC drug… read more here.
Keywords: density functional; drug; cyano hydroxycinnamic; nanocluster ... See more keywords
Surface modification of Na-K2Ti6O13 photocatalyst with Cu(II)-nanocluster for efficient visible-light-driven photocatalytic activity
Sign Up to like & getrecommendations! Published in 2018 at "Materials Letters"
DOI: 10.1016/j.matlet.2018.02.132
Abstract: Abstract A novel visible light sensitive Cu(II)-nanocluster grafted Na-K2Ti6O13 photocatalyst was prepared via molten salt method followed by impregnation technique. The prepared samples were characterized with various analytical techniques to validate the grafting of nanocluster… read more here.
Keywords: photocatalytic activity; surface; visible light; nanocluster ... See more keywords
Open Nitrogen Site-Induced Kinetic Resolution and Catalysis of a Gold Nanocluster.
Sign Up to like & getrecommendations! Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.2c04163
Abstract: The emerging metal nanocluster provides a platform for the investigation of structural features, unique properties, and structure-property correlation of nanomaterials at the atomic level. Construction of open sites on the surface of the metal nanocluster… read more here.
Keywords: open nitrogen; gold nanocluster; kinetic resolution; nanocluster ... See more keywords
Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c01053
Abstract: Due to the typical instability of copper nanoclusters, atom-precise structural elucidation of these nanoclusters has remained elusive. Herein, we report an air- and moisture-stable 23-copper nanocluster (SD/Cu23a or SD/Cu23b) isolated from the reac-tion of Cu(CF3COO)2,… read more here.
Keywords: polymorphism atomically; nanocluster; cu23 nanocluster; copper nanoclusters ... See more keywords
A New Concept of Radiation Detection Based on a Fluorochromic and Piezochromic Nanocluster.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c11496
Abstract: Developing materials that possess colorimetric responses to external stimuli is a promising strategy for addressing the current challenges in radiation dosimetry. Currently, colorimetric ionizing-radiation-responsive materials remain underexplored, and those with multistimuli response are rare. Herein,… read more here.
Keywords: nanocluster; detection based; radiation detection; radiation ... See more keywords
Optical Activity from Anisotropic-Nanocluster-Assembled Supercrystals in Achiral Crystallographic Point Groups.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12352
Abstract: Accomplishing optical activity in achiral materials has long been a challenge. Achiral nanomaterials that crystallize in achiral point groups are generally optically inactive. Herein we report the surprising observation of optical activity in several achiral… read more here.
Keywords: activity anisotropic; point groups; optical activity; activity ... See more keywords
[Au18(dppm)6Cl4]4+: a phosphine-protected gold nanocluster with rich charge states.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00042a
Abstract: A diphosphine-protected 18-gold-atom nanocluster was isolated via a facile reduction of an AuI precursor by NaBH4. Its composition was identified as {[Au18(dppm)6Cl4]·C6H6·3Cl·PF6} (SD/Au18, SD = SunDi; dppm = bis-(diphenylphosphino)methane) by X-ray single crystal structural analysis.… read more here.
Keywords: dppm 6cl4; au18 dppm; protected gold; nanocluster ... See more keywords
A high-nuclearity CuI/CuII nanocluster catalyst for phenol degradation.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01319j
Abstract: Herein, we report a 54-nuclei copper nanocluster, [Cu54S13O6(tBuS)20(tBuSO3)12] (Cu54), which is the largest atom-precise CuI/CuII mix-valent cluster reported. The Cu54 nanoclusters supported by TiO2 exhibit decent photocatalytic activity for phenol degradation under visible light. This… read more here.
Keywords: phenol degradation; nanocluster; cui cuii;
Ultrafast reproducible synthesis of a Ag-nanocluster@MOF composite and its superior visible-photocatalytic activity in batch and in continuous flow
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry A"
DOI: 10.1039/d1ta02251b
Abstract: Ultrafast synthesis of a robust Ag-nanocluster metal–organic framework composite with superior photocatalytic performances, even working under continuous flow in the removal of emerging contaminants from water. read more here.
Keywords: nanocluster; reproducible synthesis; continuous flow; ultrafast reproducible ... See more keywords
Site-specific sulfur-for-metal replacement in a silver nanocluster.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00794k
Abstract: A new Ag36 nanocluster with a closed electronic structure and eight valence electrons is reported, which has a similar structure to that of an open-shell Ag34 nanocluster with three valence electrons, except that in the… read more here.
Keywords: metal replacement; specific sulfur; sulfur metal; replacement silver ... See more keywords