Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement.
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DOI: 10.1021/acs.orglett.5c03555
Abstract: Curved nanographene 1, featuring two sp3 stereocenters, was synthesized through a Scholl-type oxidative cyclodehydrogenation accompanied by an unexpected aryl rearrangement. Single-crystal X-ray diffraction revealed that two sp3 carbons in the fused polycyclic skeleton induce pronounced… read more here.
Keywords: nanographene featuring; curved nanographene; featuring two; sp3 stereocenters ... See more keywords